Publications: Intermetallic Compounds

publications for other projects:
Metal Clusters in Solution | Hybrid Organic-Inorganic Materials

2007

download the article In Search of Cyclohexane-like Sn612-: Synthesis of Li2Ln5Sn7 (Ln = Ce, Pr, Sm, Eu) with an Open-Chain Heptane-Like Sn716- Instead Iliya Todorov and Slavi C. Sevov Inorg. Chem. 2007, 46, 4044-4048 download the article (260 KB)

2006

download the article Synthesis and Characterization of Na2Ba4Ga2Sb6 and Li13Ba8GaSb12 Iliya Todorov and Slavi C. Sevov Z. Kristallogr. 221 (2006) 521-526 download the article (324 KB)
download the article In Search of Benzene-like Sn66-: Synthesis of Na4CaSn6 with Interconnected Cyclohexane-like Sn66-. Iliya Todorov and Slavi C. Sevov Inorg. Chem. 2006, 45, 4478 download the article (202 KB)

2005

download the article Heavy-Metal Aromatic and Conjugated Species: Rings, Oligomers, and Chains of Tin in Li9-xEuSn6+x, Li9-xCaSn6+x, Li5Ca7Sn11, Li6Eu5Sn9, LiMgEu2Sn3, and LiMgSr2Sn3. Iliya Todorov and Slavi C. Sevov Inorg. Chem. 2005, 44, 5361 download the article (461 KB)

2004

download the article Heavy-Metal Aromatic Rings: Cyclopentadienyl Anion Analogues Sn56- and Pb56- in the Zintl Phases Na8BaPb6, Na8BaSn6, and Na8EuSn6. Iliya Todorov and Slavi C. Sevov Inorg. Chem. 2004, 43, 6490-6494 download the article (89.4 KB)
download the article Synthesis, Characterization, and Electronic Structure of Ba5In4Bi5: An Acentric and One-Electron Deficient Phase. Siméon Ponou, Thomas F. Fässler, Gerard Thobías, Enric Canadell, Ara Cho, and Slavi C. Sevov Chem. Eur. J. 2004, 10, 3615-3621 download the article (370 KB)

2003

download the article Synthesis and Characterization of the Zintl Pahse Na4Ba3As6 with Isolated As35- Anions. Franck Gascoin and Slavi C. Sevov J. Solid State Chem. 2003, 175, 306 download the article (154 KB)
download the article Synthesis and Characterization of Transition-Metal Zintl Phases: Cs24Nb2In12As18 and Cs13Nb2In6As10 with Isolated Complex Anions. Franck Gascoin and Slavi C. Sevov Inorg. Chem. 2003, 42, 8567-8571 download the article (79.4 KB)
download the article Synthesis and Characterization of Transition-Metal Zintl Phases: K10NbInAs6 and K9Nb2As6. Franck Gascoin and Slavi C. Sevov Inorg. Chem. 2003, 42, 904-907 download the article (58.3 KB)

2002

download the article Synthesis and Characterization of K38Nb7As24 and Cs9Nb2As6: The First Mixed-Valence Transition Metal Zintl Phases. Franck Gascoin and Slavi C. Sevov Inorg. Chem. 2002, 41, 5920 download the article (66 KB)
Highlighted in: ChemInform 2003, Jan. 28, 34
download the article Niobium-Arsenic Zintl Phases: A6NbAs5 (A = K, Rb, Cs), K6NbTlAs4, and K8NbPbAs5 with Edge-Bridged Niobium-Centered Tetrahedra of Arsenic, [NbAs4M]n- where M = As, Tl, Pb. Franck Gascoin and Slavi C. Sevov Inorg. Chem. 2002, 41, 2820-2825 download the article (74.2 KB)
download the article KBa2InAs3 with Coexisting Monomers of [In2As7]13- and Their One-Dimensional Polymers. Franck Gascoin and Slavi C. Sevov Inorg. Chem. 2002, 41, 2292-2295 download the article (121 KB)
download the article Cubane with a Handle: [{In3As4Nb} - As]7- in Cs7NbIn3As5. Franck Gascoin and Slavi C. Sevov Angew. Chem. Int. Ed. 2002, 41, 1232-1234 download the article (99.1 KB)
download the article Synthesis, Characterization and Bonding of Ba3Li4Sn8. Bobev, S.; Sevov, S.C. J. Alloys Comp. 2002, 338, 87-92 download the article (399 KB)
download the article Naked Clusters of 56 Tin Atoms in the Solid State. Bobev, S.; Sevov, S.C. J. Am. Chem. Soc. 2002, 124, 3359-3365 download the article (350 KB)
download the article Isolated Deltahedral Clusters of Lead in the Solid State: Synthesis and Characterization of Rb4Pb9 and Cs10K6Pb36 with Pb94-, and A3A'Pb4 (A = Cs, Rb, K; A' = Na, Li) with Pb44-. Bobev, S.; Sevov, S.C. Polyhedron 2002, 21, 641-649 download the article (199 KB)
contact us for a reprint Five Ternary Zintl Phases in the Systems Alkali-Metal-Indium-Bismuth. Bobev, S.; Sevov, S.C. J. Solid State Chem. 2002, 163, 436
download the chapter Zintl Phases. Sevov, S.C. in Intermetallic Compounds, Principles and Practice: Progress, Westbrook, J.H.; Freisher, R.L.: Eds.; John Wiley & Sons. Ltd., Chichester, England, 2002, pp. 113-132 download the chapter (6.10 MB)

2001

download the article Synthesis and Characterization of Cs5In3As4 with a Structure of Two Coexisting "Polymorphic" Forms of Different Dimensionality. Gascoin, F.; Sevov, S.C. Inorg. Chem. 2001, 40, 6254 download the article (81.1 KB)
download the article Synthesis and Characterization of the Largest Isolated Clusters of Tin, [Sn12]12-, in (AE)Na10Sn12 (AE = Ca or Sr). Bobev, S.; Sevov, S.C. Inorg. Chem. 2001, 40, 5361 download the article (97.4 KB)
Highlighted in: Chemistry & Industry 2001, Nov. 19, p. 742
download the article Synthesis and Characterization of the "Metallic Salts" A5Pn4 (A = K, Rb, Cs and Pn = As, Sb, Bi) with Isolated Zigzag Tetramers of Pn44- and an Extra Delocalized Electron. Gascoin, F.; Sevov, S.C. Inorg. Chem. 2001, 40, 5177 download the article (67.9 KB)
download the article Clathrate III of Group 14 Exists After All. Bobev, S.; Sevov, S.C. J. Am. Chem. Soc. 2001, 123, 3389 download the article (77 KB)
download the article Synthesis and Characterization of RbLi7Ge8 with Isolated closo-[Li4Ge12]8- Ions, Lithium-Capped Truncated Tetrahedra of Ge1212-. Bobev, S.; Sevov, S.C. Angew. Chem. Int. Ed. 2001, 40, 1507 download the article (113 KB)

2000

download the article Synthesis and Characterization of A3Na10Sn23 (A = Cs, Rb, K) with a New Clathrate-Like Structure and of the Chiral Clathrate Rb5Na3Sn25. Bobev, S.; Sevov, S.C. Inorg. Chem. 2000, 39, 5930 download the article (134 KB)
Highlighted in: Chemistry & Industry 2001, Jan. 22, p. 53
download the article arachno-[Sn8]6- or closo-[Li2Sn8]4-? Synthesis and Characterization of A4Li2Sn8 (A = Rb, K). Bobev, S.; Sevov, S.C. Angew. Chem. Int. Ed. 2000, 39, 4108 download the article (92.2 KB)
download the article Synthesis and Characterization of A3Bi2 (A = K, Rb, Cs) with Isolated Diatomic Dianion of Bismuth, [Bi2]2-, and an Extra Delocalized Electron. Gascoin, F.; Sevov, S.C. J. Am. Chem. Soc. 2000, 122, 10251 download the article (39.2 KB)
download the article Clathrates of Group 14 with Alkali Metals: An Exploration. Bobev, S.; Sevov, S.C. J. Solid State Chem. 2000, 153, 92 download the article (373 KB)
Cover Page: J. Solid State Chem. 2000, vol. 153, No. 2
download the article Synthesis and Structure of the Alkali-Metal Amalgams A3Hg20 (A = Rb, Cs), K3Hg11, Cs5Hg19, and A7Hg31 (A = K, Rb). Todorov, E.; Sevov, S.C. J. Solid State Chem. 2000, 149, 419 download the article (465 KB)

1999

download the article K6Pb8Cd: A Zintl Phase with Oligomers of Pb4 Tetrahedra Interconnected by Cd Atoms. Todorov, E.; Sevov, S.C. Angew. Chem. Int. Ed. 1999, 38, 1775 download the article (111 KB)
download the article Cs7In4Bi6: A Zintl Phase Tailored from the PbO-Type Layers of the Parent InBi Compound. Bobev, S.; Sevov, S.C. Inorg. Chem. 1999, 38, 2672 download the article (255 KB)
download the article Synthesis and Characterization of Stable Stoichiometric Clathrates of Silicon and Germanium: Cs8Na16Si136 and Cs8Na16Ge136. Bobev, S.; Sevov, S.C. J. Am. Chem. Soc. 1999, 121, 3795 download the article (36 KB)
Highlighted in: Chemistry & Industry 1999, May 17, p. 401

1998

download the article Intermetallic Frameworks: Synthesis, Characterization, and Bonding of K0.4Cd2 and Na26Cd141. Todorov, E.; Sevov, S.C. Inorg. Chem. 1998, 37, 6341 download the article (133 KB)
download the article Deltahedral Clusters in Neat Solids: Synthesis and Structure of the Zintl Phase Cs4Pb9 with Discrete Pb94- Clusters. Todorov, E.; Sevov, S.C. Inorg. Chem. 1998, 37, 3889 download the article (80.3 KB)
download the article Synthesis and Structure of Isolated Silicon Clusters of Nine Atoms. Quéneau, V.; Todorov, E.; Sevov, S.C. J. Am. Chem. Soc. 1998, 120, 3263 download the article (90.3 KB)
Highlighted in: C & EN 1998, April 13, p. 40
download the article Synthesis and Structure of the Zintl-Phase K4Pb9 Containing Isolated Pb94- Clusters of Two Different Geometries. Quéneau, V.; Sevov, S.C. Inorg. Chem. 1998, 37, 1358 download the article (98.9 KB)

1997

download the article Synthesis, Characterization, and Bonding of Heteroatomic Clusters: Na13Cd20E7 (E = Pb, Sn), a Further Example of a Structure Containing Empty Icosahedra without an Element of Group 13. Todorov, E.; Sevov, S.C. Inorg. Chem. 1997, 36, 4298 download the article (136 KB)
Highlighted in: Chemistry & Industry 1997, Oct. 20, p. 83
contact us for a reprint Ge94-: A Deltahedral Zintl Ion Made in the Solid State. Quéneau, V.; Sevov, S.C. Angew. Chem. Int. Ed. Engl. 1997, 36, 1754
download the article Cs6Ge8Zn: A Zintl Phase with Isolated Heteroatomic Clusters of Ge8Zn. Quéneau, V.; Sevov, S.C. J. Am. Chem. Soc. 1997, 119, 8109 download the article (143 KB)
download the article Synthesis, Characterization, Electronic Structure, and Bonding of Heteroatomic Deltahedral Clusters: Na49Cd58.5Sn37.5, A Network Structure Containing The First Empty Icosahedron without a Group 13 Element and the Largest closo-Deltahedron. Todorov, E.; Sevov, S.C. J. Am. Chem. Soc. 1997, 119, 2869 download the article (185 KB)

publications for other projects:
Metal Clusters in Solution | Hybrid Organic-Inorganic Materials

last revised: Apr 15, 2011
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