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  2. Publications

List of Publications

  • 2024

    51. Directed C-H Activation with Iron Carbene Complexes
    Zachary S. Lincoln, Melissa R. Hoffbauer and Vlad M. Iluc
    Inorganic Chemistry Frontiers - July 18, 2024

     

    Inorg. Chem. Front. 2024, 11, 5579-5586. [LINK]

    50. Iron Olefin Metathesis: Unlocking Reactivity and Mechanistic Insights
    Zachary S. Lincoln and Vlad M. Iluc
    Journal of the American Chemical Society - June 18, 2024

     

    J. Am. Chem. Soc. 2024, 146 (26), 17595–17599. [LINK]

  • 2021

    49. [2+2] Cycloadditions with an Iron Carbene: A Critical Step in Enyne Metathesis
    Melissa R. Hoffbauer and Vlad M. Iluc
    Journal of the American Chemical Society - April 8, 2021

     

    J. Am. Chem. Soc. 2021, 143 (15), 5592–5597. [LINK]

    48. The Coordination Chemistry of Low-Valent Nickel, Palladium, and Platinum
    Cody R. Work and Vlad M. Iluc
    Comprehensive Coordination Chemistry III (Third Edition) - May 31, 2021

     

    Comprehensive Coordination Chemistry III (Third Edition) 2021, 6, 229-347. [LINK]

  • 2019

    47. Oxidation Reactions of a Nucleophilic Palladium Carbene: Mono and Bi-radical Carbenes
    Peng Cui, Melissa R. Hoffbauer, Mariya Vyushkova, and Vlad M. Iluc
    CDalton Transactions - March 12, 2019; Special Issue: International Year of the Periodic Table : d-Block

     

    Dalton Trans. 2019, 48, 16948-16952. [LINK]

    46. Square Planar Nucleophilic and Radical Pt(II) Carbenes
    Anthony P. Deziel, Melissa R. Hoffbauer and Vlad M. Iluc
    Organometallics - February 15, 2019

     

    Organometallics 2019, 38 (4), 879-887. [LINK]

    45. Reactivity of a Pd(II) Carbene towards 2,6-dimesitylphenyldiazomethane and 2,6-dimesitylphenylazide
    Melissa R. Hoffbauer, Cezar C. Comanescu and Vlad M. Iluc
    Polyhedron - November 16, 2018; Special Issue for William Jones

     

    Polyhedron 2019, 158, 352-356. [LINK]

  • 2018

    44. Influence of the Leaving Group on C-H Activation Pathways in Palladium Pincer Complexes
    Melissa R. Hoffbauer, Cezar C. Commanescu, Brittany J. Dymm and Vlad M. Iluc
    Organometallics - June 26, 2018

     

    Organometallics 2018, 37 (13), 2086-2094. [LINK]

    43. Pincer Carbenoid Complexes With Late Transition Metals: Synthesis, Electronic Structure, and Reactivity
    Peng Cui and Vlad M. Iluc
    Pincer Compounds - 2018

     

    Pincer Compounds 2018, 359-381. [LINK]

    42. E-H (E = N, O) Bond Activation by a Nucleophilic Palladium Carbene
    Cezar C. Comanescu and Vlad M. Iluc
    CPolyhedron - October 13, 2017; Special Issue: Pincer Ligands

     

    Polyhedron 2018, 143, 176-183. [LINK]

  • 2017

    41. Formation of Palladium η2-bound Chalcogenoketones across a Pd+−C- Bond
    Patrick E. Rothstein, Cezar C. Comanescu and Vlad M. Iluc
    Chemistry: A European Journal - September 5, 2017

     

    Chem. Eur. J. 2017, 23 (167), 16948-16952. [LINK]

    40. Ni(II) Phosphine and Phosphide Complexes Supported by a PNP-Pyrrole Pincer Ligand
    Julie A. Kessler and Vlad M. Iluc
    Dalton Transactions - August 29, 2017

     

    Dalton Trans. 2017, 46, 12125-12131. [LINK]

    39. Iron Pyrrole-Based PNP Pincer Ligand Complexes as Catalyst Precursors
    Amanda M. Holland, Allen G. Oliver, and Vlad M. Iluc
    Acta Crystallographica Section C: Structural Chemistry - June 28, 2017

     

    Acta Crystallogr., Sect. C: Struct. Chem. 2017, C73, 569-574. [LINK]

    38. An Adaptable Chelating Diphosphine Ligand for the Stabilization of Palladium and Platinum Carbenes
    Brittany J. Barret and Vlad M. Iluc
    Organometallics - January 20, 2017 - Open Access Article

     

    Organometallics 2017, 36 (3), 730–741 .[LINK]

    37. Metal-Ligand Cooperation between Palladium and a Diphosphine Ligand With an Olefinic Backbone
    Brittany J. Barret and Vlad M. Iluc
    Inorganica Chimica Acta - August 20, 2016; Special Issue: Next Generation

     

    Inorg. Chim. Acta. 2017, 460, 35-42. [LINK]

  • 2016

    36. Aryl and Benzyl CH Activation of N-Substituted PNP Ligands
    Sean P. Vilanova and Vlad M. Iluc
    Organometallics - June 14, 2016

     

    Organometallics 2016, 35 (12), 2110–2123 [LINK]

    35. Heterobimetallic Pd-K Carbene Complexes via One-Electron Reductions of Palladium Radical Carbenes
    Peng Cui, Melissa R. Hoffbauer, Mariya Vyushkova and Vlad M. Iluc
    CChemical Science - March 24, 2016

     

    Chem. Sci. 2016, 7, 4444-4452. [LINK]

    34. C-H Activation of Ethers by Pyridine Tethered PCsp3P-type Iridium Complexes
    Peng Cui, Dominic C. Babbini and Vlad M. Iluc
    Dalton Transactions - March 17, 2016; Themed issue: 2016 New Talent Americas across academia and the U.S. National Laboratories

     

    Dalton Trans. 2016, 45, 10007-10016. [LINK]

    33. E-H (E = B, Si, Ge) Bond Activation of Pinacolborane, Silanes, and Germanes by Nucleophilic Palladium Carbene Complexes
    Cezar C. Comanescu and Vlad M. Iluc
    Chemical Communications - January 21, 2016; Themed issue: 2016 Emerging Investigators

     

    Chem. Commun. 2016, 52, 9048-9051. [LINK]

  • 2015

    32. Redox-Induced Umpolung of Transition Metal Carbenes
    Peng Cui and Vlad M. Iluc
    Chemical Science - September 25, 2015

     

    Chem. Sci. 2015, 6, 7343-7354. [LINK]

    31. C-H Activation Reactions of a Nucleophilic Palladium Carbene
    Cezar C. Comanescu and Vlad M. Iluc
    Organometallics - July 9, 2015 - Open Access Article

     

    Organometallics 2015, 34 (19), 4684-4692. [LINK]

    30. Iridium PCsp3P-type Complexes with a Hemilabile Anisole Tether
    Dominic C. Babbini and Vlad M. Iluc
    Organometallics - June 24, 2015

     

    Organometallics 2015, 34 (13), 3141-3151. [LINK]

    29. Palladium Carbene Complexes as Persistent Radicals
    Cezar C. Comanescu, Mariya Vyushkova and Vlad M. Iluc
    Chemical Science - May 18, 2015

     

    Chem. Sci. 2015, 6, 4570-4579. [LINK]

    28. Frustrated Lewis Pair-Like Reactions of Nucleophilic Palladium Carbenes with B(C6F5)3
    Peng Cui, Cezar C. Comanescu and Vlad M. Iluc
    Chemical Communications - March 3, 2015

     

    Chem. Commun. 2015, 51, 6206-6209. [LINK]

  • 2014

    27. Ag(I) and Tl(I) Precursors as Transfer Agents of a Pyrrole-based Pincer Ligand to Late Transition Metals
    Julie A. Kessler and Vlad M. Iluc
    Inorganic Chemistry - November 11, 2014

     

    Inorg. Chem. 2014, 53 (23), 12360-12371. [LINK]

    26. Synthesis and Reactivity of a Nucleophilic Palladium(II) Carbene
    Cezar C. Comanescu and Vlad M. Iluc
    Organometallics - October 07, 2014 - Open Access Article

     

    Organometallics 2014, 33 (21), 6059–6064. [LINK]

    25. Flexible Coordination of Diphosphine Ligands Leading to cis and trans Pd(0), Pd(II), and Rh(I) Complexes
    Cezar C. Comanescu and Vlad M. Iluc
    Inorganic Chemistry - August 07, 2014 - Open Access Article

     

    Inorg. Chem. 2014, 53 (16), 8517-8528. [LINK]

    24. Coordination of a Hemilabile Pincer Ligand with an Olefinic Backbone to Mid-to-Late Transition Metals
    Brittany J. Barrett and Vlad M. Iluc
    Inorganic Chemistry - June 24, 2014 - Open Access Article

     

    Inorg. Chem. 2014, 53 (14), 7248-7259. [LINK]

    23. Group 10 Metal Complexes Supported by a Pincer Ligand with an Olefinic Backbone
    Brittany J. Barrett and Vlad M. Iluc
    Organometallics - May 13, 2014 - Open Access Article

     

    Organometallics 2014, 33 (10), 2565-2574. [LINK]

  • Undergraduate, Graduate, and Postdoctoral Work

    22. Mindiola, Daniel J.; Waterman, Rory; Iluc, Vlad M.; Cundary, Thomas R.; Hillhouse, Gregory L. "Carbon–Hydrogen Bond Activation, C–N Bond Coupling, and Cycloaddition Reactivity of a Three-Coordinate Nickel Complex Featuring a Terminal Imido Ligand." Inorganic Chemistry 2014, 53(24), 13227-13238. [LINK]

    21. Iluc, Vlad M.; Hillhouse, Gregory L. "Three-Coordinate Nickel Carbene Complexes and Their One-Electron Oxidation Products" Journal of the American Chemical Society 2014, 136(17), 6479-6488. [[LINK]

    20. Laskowski, Carl A.; Bungum, Donald J.; Baldwin Steven M.; Del Ciello, Sarah A.; Iluc, Vlad M.; Hillhouse, Gregory L. "Synthesis and Reactivity of Two-Coordinate Ni(I) Alkyl and Aryl Complexes" Journal of the American Chemical Society 2013, 135(49), 18272-18275. [LINK]

    19. Iluc, Vlad M.; Fedorov, Alexey; Grubbs, Robert H. "H/D Exchange Processes Catalyzed by an Iridium-Pincer Complex" Organometallics 2012, 31(1), 39-41. [LINK]

    18. Iluc, Vlad M.; Miller, Alexander J. M.; Anderson, John S.; Monreal, Marsia J.; Mehn, Mark P.; Hillhouse, Gregory L. "Synthesis and Characterization of Three-Coordinate Ni(III)-Imide Complexes" Journal of the American Chemical Society 2011, 133(33), 13055–13063. [LINK]

    17. Iluc, Vlad M..; Hillhouse, Gregory L. "Hydrogen-Atom Abstraction from Ni(I) Phosphido and Amido Complexes Gives Phosphinidene and Imide Ligands" Journal of the American Chemical Society 2010, 132(43), 15148–15150. [LINK]

    16. Anderson, John S.; Iluc, Vlad M.; Hillhouse, Gregory L. "Reactions of CO2 and CS2 with 1,2-Bis(di-tert-butyl-phosphino)-ethane complexes of Nickel(0) and Nickel(I)" Inorganic Chemistry 2010, 49(21), 10203–10207. [LINK]

    15. Iluc, Vlad M.; Hillhouse, Gregory L. "Arrested 1,2-Hydrogen Migration from Silicon to Nickel upon Oxidation of a Three-Coordinate Ni(I) Silyl Complex" Journal of the American Chemical Society 2010, 132(34), 11890-11892. [LINK]

    14. Iluc, Vlad M.; Laskowski, Carl A.; Brozek, Carl K. Harrold, Nicole D.; Hillhouse, Gregory L. "Monomeric and Dimeric Disulfide Complexes of Nickel(II)" Inorganic Chemistry 2010, 49(15), 6817-6819. [LINK]

    13. Iluc, Vlad M.; Laskowski, Carl A.; Hillhouse, Gregory L. Synthesis of Bis(phosphine) and N-Heterocyclic Carbene Supported α-Diazoalkyl Complexes of Copper(I)" Organometallics 2009, 28(20), 6135-6138. [LINK]

    12. Iluc, Vlad M.; Hillhouse, Gregory L. "Snapshots of the oxidative-addition process of silanes to nickel(0)" Tetrahedron 2006, 62(32), 7577-7582.[LINK]

    11. Iluc, Vlad M.; Miller, Alexander J. M.; Hillhouse, Gregory L. "Synthesis and characterization of side-bound aryldiazo and end-bound nitrosyl complexes of nickel" Chemical Communications 2005, 40, 5091-5093. [LINK]

    10. Guran, Cornelia; Barboiu, Mihai; Diaconescu, Paula; Iluc, Vlad; Stan, Claudiu "Mono and polynuclear complexes of Cr(III) with dichloro-tetramorpholino-cyclotriphosphazatriene" Revue Roumaine de Chimie 2000, 44(9), 917-921.

    9. Guran, Cornelia; Diaconescu, Paula; Barboiu, Mihai; Iluc, Vlad; Stan, Claudiu "Heteropolynuclear complex precursors used in mixed oxide synthesis" British Ceramic Proceedings 2000, 61, 33-39.

    8. Guran, Cornelia; Iluc, Vlad; Diaconescu, Paula; Bicher, Mariana; Ciocoiu, Calin "Pyridazinyl-hydrazine derivatives as polydentate ligand generators of Pt(II) and Pd(II) cis-complexes" Roumanian Biotechnological Letters 1999, 4(5), 369-374.

    7. Barboiu, Mihai; Supuran, Claudiu T.; Scozzafava, Andrea; Guran, Cornelia; Diaconescu, Paula; Bojin, Mihaela; Iluc, Vlad; Cot, Louis "Functionalized derivatives of benzo-crown ethers. Part 4. Antifungal macrocyclic supramolecular complexes of transition metal ions acting as lanosterol-14-α-demethylase inhibitors" Metal-Based Drugs 1999, 6(2), 101-110.

    6. Bacu, Elena; Guran, Cornelia; Ciocoiu, Ioana; Iluc, Vlad "Complex compounds of Cu(II) with phenothiazine derivatives as biological active ligands" Analele Stiintifice ale Universitatii "Al. I. Cuza" din Iasi, Chimie 1998, 6, 29-34.

    5. Guran, Cornelia; Barboiu, Mihai; Diaconescu, Paula; Iluc, Vlad; Bojin, Mihaela; Scozzafava, Andrea; Supuran, Claudiu T. "Synthesis and antifungal activity of metal complexes containing dichloro-tetramorpholino-cyclophosphazatriene" Metal-Based Drugs 1998, 5(5), 287-294.

    4. Guran, Cornelia; Bacu, Elena; Ciocoiu, Ioana; Carp, Nicoleta; Iluc, Vlad; Diaconescu, Paula; Bojin, Mihaela; Nicolae, Simona "Complex compounds with phenothiazine derivatives as biologically active ligands. 4. Mono and polynuclear complex compounds of Fe(III)" Roumanian Biotechnological Letters 1998, 3(2), 123-130.

    3. Guran, Cornelia; Barboiu, Mihai; Meghea, Aurelia; Jitaru, Ioana; Cimpoesu, Marilena; Berger, Daniela; Diaconescu, Paula; Bojin, Mihaela; Iluc, Vlad; Bita, Ion "Contribution to the cyclophosphazene chemistry. 3. Complex compounds of Cu(II) with substituted cyclophosphazatriene derivatives" Revue Roumaine de Chimie 1997, 42(7), 609-614.

    2. Guran, Cornelia; Bicu, Elena; Jitaru, Ioana; Ciocoiu, Ioana; Meghea, Aurelia; Iluc, Vlad; Bojin, Mihaela; Diaconescu, Paula "Complex compounds of copper(II) with phenothiazine derivatives" Revue Roumaine de Chimie 1997, 42(9), 891-896.

    1. Guran, Cornelia; Bicu, Elena; Ciocoiu, Ioana; Bojin, Mihaela; Diaconescu, Paula; Iluc, Vlad; Jinga, Oana "Complex compounds with phenothiazine derivatives as biological active ligands III" Roumanian Biotechnological Letters 1997, 2(3), 243-252.

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