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Heavy-Metal Aromatic Rings: Cyclopentadienyl Anion Analogues Sn56- and Pb56- in the Zintl Phases Na8BaPb6, Na8BaSn6, and Na8EuSn6. Iliya Todorov and Slavi C. Sevov Inorg. Chem. 2004, 43, 6490-6494 (89.4 KB) |
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Synthesis, Characterization, and Electronic Structure of Ba5In4Bi5: An Acentric and One-Electron Deficient Phase. Siméon Ponou, Thomas F. Fässler, Gerard Thobías, Enric Canadell, Ara Cho, and Slavi C. Sevov Chem. Eur. J. 2004, 10, 3615-3621 (370 KB) |
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Synthesis and Characterization of K38Nb7As24 and Cs9Nb2As6: The First Mixed-Valence Transition Metal Zintl Phases. Franck Gascoin and Slavi C. Sevov Inorg. Chem. 2002, 41, 5920 (66 KB) Highlighted in: ChemInform 2003, Jan. 28, 34 |
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Niobium-Arsenic Zintl Phases: A6NbAs5 (A = K, Rb, Cs), K6NbTlAs4, and K8NbPbAs5 with Edge-Bridged Niobium-Centered Tetrahedra of Arsenic, [NbAs4M]n- where M = As, Tl, Pb. Franck Gascoin and Slavi C. Sevov Inorg. Chem. 2002, 41, 2820-2825 (74.2 KB) |
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KBa2InAs3 with Coexisting Monomers of [In2As7]13- and Their One-Dimensional Polymers. Franck Gascoin and Slavi C. Sevov Inorg. Chem. 2002, 41, 2292-2295 (121 KB) |
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Cubane with a Handle: [{In3As4Nb} - As]7- in Cs7NbIn3As5. Franck Gascoin and Slavi C. Sevov Angew. Chem. Int. Ed. 2002, 41, 1232-1234 (99.1 KB) |
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Synthesis, Characterization and Bonding of Ba3Li4Sn8. Bobev, S.; Sevov, S.C. J. Alloys Comp. 2002, 338, 87-92 (399 KB) |
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Naked Clusters of 56 Tin Atoms in the Solid State. Bobev, S.; Sevov, S.C. J. Am. Chem. Soc. 2002, 124, 3359-3365 (350 KB) |
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Isolated Deltahedral Clusters of Lead in the Solid State: Synthesis and Characterization of Rb4Pb9 and Cs10K6Pb36 with Pb94-, and A3A'Pb4 (A = Cs, Rb, K; A' = Na, Li) with Pb44-. Bobev, S.; Sevov, S.C. Polyhedron 2002, 21, 641-649 (199 KB) |
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Five Ternary Zintl Phases in the Systems Alkali-Metal-Indium-Bismuth. Bobev, S.; Sevov, S.C. J. Solid State Chem. 2002, 163, 436 |
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Zintl Phases. Sevov, S.C. in Intermetallic Compounds, Principles and Practice: Progress, Westbrook, J.H.; Freisher, R.L.: Eds.; John Wiley & Sons. Ltd., Chichester, England, 2002, pp. 113-132 (6.10 MB) |
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Synthesis and Characterization of Cs5In3As4 with a Structure of Two Coexisting "Polymorphic" Forms of Different Dimensionality. Gascoin, F.; Sevov, S.C. Inorg. Chem. 2001, 40, 6254 (81.1 KB) |
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Synthesis and Characterization of the Largest Isolated Clusters of Tin, [Sn12]12-, in (AE)Na10Sn12 (AE = Ca or Sr). Bobev, S.; Sevov, S.C. Inorg. Chem. 2001, 40, 5361 (97.4 KB) Highlighted in: Chemistry & Industry 2001, Nov. 19, p. 742 |
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Synthesis and Characterization of the "Metallic Salts" A5Pn4 (A = K, Rb, Cs and Pn = As, Sb, Bi) with Isolated Zigzag Tetramers of Pn44- and an Extra Delocalized Electron. Gascoin, F.; Sevov, S.C. Inorg. Chem. 2001, 40, 5177 (67.9 KB) |
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Clathrate III of Group 14 Exists After All. Bobev, S.; Sevov, S.C. J. Am. Chem. Soc. 2001, 123, 3389 (77 KB) |
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Synthesis and Characterization of RbLi7Ge8 with Isolated closo-[Li4Ge12]8- Ions, Lithium-Capped Truncated Tetrahedra of Ge1212-. Bobev, S.; Sevov, S.C. Angew. Chem. Int. Ed. 2001, 40, 1507 (113 KB) |
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Synthesis and Characterization of A3Na10Sn23 (A = Cs, Rb, K) with a New Clathrate-Like Structure and of the Chiral Clathrate Rb5Na3Sn25. Bobev, S.; Sevov, S.C. Inorg. Chem. 2000, 39, 5930 (134 KB) Highlighted in: Chemistry & Industry 2001, Jan. 22, p. 53 |
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arachno-[Sn8]6- or closo-[Li2Sn8]4-? Synthesis and Characterization of A4Li2Sn8 (A = Rb, K). Bobev, S.; Sevov, S.C. Angew. Chem. Int. Ed. 2000, 39, 4108 (92.2 KB) |
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Synthesis and Characterization of A3Bi2 (A = K, Rb, Cs) with Isolated Diatomic Dianion of Bismuth, [Bi2]2-, and an Extra Delocalized Electron. Gascoin, F.; Sevov, S.C. J. Am. Chem. Soc. 2000, 122, 10251 (39.2 KB) |
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Clathrates of Group 14 with Alkali Metals: An Exploration. Bobev, S.; Sevov, S.C. J. Solid State Chem. 2000, 153, 92 (373 KB) Cover Page: J. Solid State Chem. 2000, vol. 153, No. 2 |
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Synthesis and Structure of the Alkali-Metal Amalgams A3Hg20 (A = Rb, Cs), K3Hg11, Cs5Hg19, and A7Hg31 (A = K, Rb). Todorov, E.; Sevov, S.C. J. Solid State Chem. 2000, 149, 419 (465 KB) |
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K6Pb8Cd: A Zintl Phase with Oligomers of Pb4 Tetrahedra Interconnected by Cd Atoms. Todorov, E.; Sevov, S.C. Angew. Chem. Int. Ed. 1999, 38, 1775 (111 KB) |
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Cs7In4Bi6: A Zintl Phase Tailored from the PbO-Type Layers of the Parent InBi Compound. Bobev, S.; Sevov, S.C. Inorg. Chem. 1999, 38, 2672 (255 KB) |
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Synthesis and Characterization of Stable Stoichiometric Clathrates of Silicon and Germanium: Cs8Na16Si136 and Cs8Na16Ge136. Bobev, S.; Sevov, S.C. J. Am. Chem. Soc. 1999, 121, 3795 (36 KB) Highlighted in: Chemistry & Industry 1999, May 17, p. 401 |
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Intermetallic Frameworks: Synthesis, Characterization, and Bonding of K0.4Cd2 and Na26Cd141. Todorov, E.; Sevov, S.C. Inorg. Chem. 1998, 37, 6341 (133 KB) |
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Deltahedral Clusters in Neat Solids: Synthesis and Structure of the Zintl Phase Cs4Pb9 with Discrete Pb94- Clusters. Todorov, E.; Sevov, S.C. Inorg. Chem. 1998, 37, 3889 (80.3 KB) |
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Synthesis and Structure of Isolated Silicon Clusters of Nine Atoms. Quéneau, V.; Todorov, E.; Sevov, S.C. J. Am. Chem. Soc. 1998, 120, 3263 (90.3 KB) Highlighted in: C & EN 1998, April 13, p. 40 |
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Synthesis and Structure of the Zintl-Phase K4Pb9 Containing Isolated Pb94- Clusters of Two Different Geometries. Quéneau, V.; Sevov, S.C. Inorg. Chem. 1998, 37, 1358 (98.9 KB) |
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Synthesis, Characterization, and Bonding of Heteroatomic Clusters: Na13Cd20E7 (E = Pb, Sn), a Further Example of a Structure Containing Empty Icosahedra without an Element of Group 13. Todorov, E.; Sevov, S.C. Inorg. Chem. 1997, 36, 4298 (136 KB) Highlighted in: Chemistry & Industry 1997, Oct. 20, p. 83 |
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Ge94-: A Deltahedral Zintl Ion Made in the Solid State. Quéneau, V.; Sevov, S.C. Angew. Chem. Int. Ed. Engl. 1997, 36, 1754 |
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Cs6Ge8Zn: A Zintl Phase with Isolated Heteroatomic Clusters of Ge8Zn. Quéneau, V.; Sevov, S.C. J. Am. Chem. Soc. 1997, 119, 8109 (143 KB) |
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Synthesis, Characterization, Electronic Structure, and Bonding of Heteroatomic Deltahedral Clusters: Na49Cd58.5Sn37.5, A Network Structure Containing The First Empty Icosahedron without a Group 13 Element and the Largest closo-Deltahedron. Todorov, E.; Sevov, S.C. J. Am. Chem. Soc. 1997, 119, 2869 (185 KB) |