Publications: Metal Clusters in Solution

publications for other projects:
Intermetallic Compounds | Hybrid Organic-Inorganic Materials

2016

download the article [Me3Si]3EtGe9Pd(PPh3), a Pentafunctionalized Deltahedral Zintl Cluster: Synthesis, Structure, and Solution Dynamics Feng Li, Alvaro Munoz-Castro, and Slavi C. Sevov Angew. Chem. Int. Ed. 2016, Accepted.download the article (1.71 MB)
download the article Cluster Fusion: Face-Fused Nine-Atom Deltahedral Clusters in [Sn14Ni(CO)]4 Luis G. Perla and Slavi C. Sevov Angew. Chem. Int. Ed. 2016, 55, 6721. download the article (1.35 MB)

2015

download the article [Bi12Ni7(CO)4]4-: Aggregation of Intermetalloid Clusters by Their Thermal Deligation and Oxidation Luis G. Perla and Slavi C. Sevov Inorg. Chem. 2015, 54, 8401. download the article (1.71 MB)
download the article Coordination of Tri-substituted Nona-Germanium Clusters to Cu(I) and Pd(0) Feng Li and Slavi C. Sevov Inorg. Chem. 2015, 54, 8121. download the article (1.41 MB)
download the article Bi73-: The Missing Family Member, Finally Isolated and Characterized Luis G. Perla, Allen G. Oliver, and Slavi C. Sevov Inorg. Chem. 2015, 54, 872. download the article (1.10 MB)

2014

download the article Synthesis, Structures, and Solution Dynamics of Tetrasubstituted Nine-Atom Germanium Deltahedral Clusters Feng Li and Slavi C. Sevov J. Am. Chem. Soc. 2014, 136, 12056. download the article (1.35 MB)

2013

download the article Tri-metallic deltahedral Zintl ions [Sn9-m-nGemBin](4-n)- for n = 1-4 and m = 0-(9-n): A theoretical survey with prediction and rationalization of the possible structures Alvaro Munoz-Castro and Slavi C. Sevov Phys. Chem. Chem. Phys. 2013, 15, 986. download the article (1.9 MB)

2012

download the article Ultra-broad near-infrared photoluminescence from crystalline (K-crypt)2Bi2 containing [Bi2]2- dimers Hong-Tao Sun, Tetsu Yonezawa, Miriam M. Gillett-Kunnath, Yoshio Sakka, Naoto Shirahata, Sa Chu Rong Gui, Minoru Fujii and Slavi C. Sevov J. Mater. Chem. 2012, 22, 20175. download the article (198 KB)
download the article [Ge9{Si(SiMe3)3}3{SnPh3}]: A Tetra-Substituted Deltahedral Nine-Atom Cluster Feng Li, Alvaro Munoz-Castro and Slavi C. Sevov Angew. Chem. Int. Ed. 2012, 51, 8581. download the article (397 KB)
download the article Developing organo-Zintl deltahedral clusters as ligands for coordination to transition-metals via their organic tethers Michael W. Hull and Slavi C. Sevov J. Organometallic Chem. 2012, 721, 85. download the article (933 KB)
download the article Water Compatibility and Organic Transformations of Organo-Zintl Deltahedral Clusters Michael W. Hull and Slavi C. Sevov Chem. Commun. 2012, 48, 7720. download the article (1.6 MB)
download the article Tri-metallic deltahedral Zintl ions: Experimental and theoretical studies of the novel dimer [(Sn6Ge2Bi)2]4- Miriam M. Gillett-Kunnath, Alvaro Munoz-Castro and Slavi C. Sevov Chem. Commun. 2012, 48, 3524. download the article (426 KB)
download the article Synthesis of Nine-atom Deltahedral Zintl Ions of Germanium and their Functionalization with Organic Groups Miriam M. Gillett-Kunnath and Slavi C. Sevov Journal of Visualized Experiments 2012, 60, e3532. download the article (1.2 MB) Watch Video Online!
download the article Rational Synthesis of [Ge9{Si(SiMe3)3}3]- from Its Parent Zintl Ion Ge94- Feng Li and Slavi C. Sevov Inorg. Chem. 2012, 51, 2706. download the article (903 KB)

2011

download the article Metal-Centered Deltahedral Zintl Ions: Synthesis of [Ni@Sn9]4- by Direct Extraction from Intermetallic Precursors and of the Vertex-Fused Dimer [{Ni@Sn8(μ-Ge)1/2}2]4- Miriam M. Gillett-Kunnath, Joseph I. Paik, Sara M. Jensen, Jacob D. Taylor, and Slavi C. Sevov Inorg. Chem. 2011, 50, 11695-11701. download the article (2.75 MB)
download the article "n-Doping" of Deltahedral Zintl Ions Miriam M. Gillett-Kunnath, Allen G. Oliver and Slavi C. Sevov J. Am. Chem. Soc. 2011, 133, 6560-6562. download the article (1.32 MB)
download the article Addition of a Thallium Vertex to Empty and Centered Nine-Atom Deltahedral Zintl Ions of Germanium and Tin Daniel Rios, Miriam M. Gillett-Kunnath, Jacob D. Taylor, Allen G. Oliver and Slavi C. Sevov Inorg. Chem. 2011, 50, 2373-2377. download the article (2 MB)

2010

download the article The Elusive closo-Ge102- Zintl Ion: Finally "Captured" as a Ligand in the Complex [Ge10Mn(CO)4]3- Daniel Rios and Slavi C. Sevov Inorg. Chem. 2010, 49, 6396-6398 download the article (7.66 MB)
download the article Anodic Electrodeposition of Germanium Films from Ethylenediamine Solutions of Deltahedral Ge94- Zintl Ions Nirmala Chandrasekharan and Slavi C. Sevov Journal of the Electrochemical Society 2010, 157 (4), C140-C145 download the article (8.44 MB)
download the article Heteroatomic Deltahedral Zintl Ions of Group 14 and their Alkenylation Miriam M. Gillett-Kunnath, Ivaylo Petro and Slavi C. Sevov Inorg. Chem. 2010, 49, 721-729 download the article (3.6 MB)

2009

download the article Functionalization of Nine-Atom Deltahedral Zintl Ions with Organic Substituents: Detailed Studies of the Reactions Michael W. Hull and Slavi C. Sevov J. Am. Chem. Soc. 2009, 131, 9026-9037 download the article (4.3 MB)

2008

download the article Tin Zintl Ions: Synthesis, Structure, and Reactivity, Slavi C. Sevov in Tin Chemistry: Fundamentals, Frontiers, and Applications, Eds.: Marcel Gielen, Alwyn Davies, Keith Pannell, Edward Tiekink, Wiley-VCH, 2008, pp. 138-150 download the article (1.1 MB)
download the article Tin-Based Organo-Zintl Ions: Alkylation and Alkenylation of Sn94- Donald J. Chapman and Slavi C. Sevov Inorg. Chem. 2008, 47, 6009-6013 download the article (267 KB)

2007

download the article Organo-Zintl Clusters Soluble in Conventional Organic Solvents: Setting the Stage for Organo-Zintl Cluster Chemistry Michael W. Hull and Slavi C. Sevov Inorg. Chem. 2007, 46, 10953 download the article (68 KB)
download the article Addition of Alkenes to Deltahedral Zintl Clusters by Reaction with Alkynes: Synthesis and Structures of [Fc-CH=CH-Ge9-CH=CH-Fc]2-, an Organo-Zintl-Organometallic Anion Michael W. Hull and Slavi C. Sevov Angew. Chem. Int. Ed. 2007, 46, 6695 download the article (144 KB)
download the article Heteroatomic Deltahedral Clusters: Synthesis and Structures of closo-[Bi3Ni4(CO)6]3-, closo-[Bi4Ni4(CO)6]2-, the Open Cluster [Bi3Ni6(CO)9]3-, and the Intermetalloid closo-[Nix@{Bi6Ni6(CO)8}]4- Jose M. Goicoechea, Michael W. Hull, and Slavi C. Sevov J. Am. Chem. Soc 2007, 129, 7885-7893 download the article (324 KB)
download the article Alkylation of Deltahedral Zintl Clusters: Synthesis of [R-Ge9-Ge9-R]4- (R = tBu, sBu, nBu, tAm) and Structure of [tBu-Ge9-Ge9-tBu]4- Michael W. Hull, Angel Ugrinov, Ivaylo Petrov, and Slavi C. Sevov Inorg. Chem. 2007, 46, 2704 download the article (112 KB)

2006

download the article Chemistry of Deltahedral Zintl Ions Slavi C. Sevov and Jose M. Goicoechea Organometallics 2006, 25, 5678 download the article (6 MB)
download the article [Zn9Bi11]5-: A Ligand-Free Intermetalloid Cluster Jose M. Goicoechea and Slavi C. Sevov, Angew. Chem. Int. Ed. 2006, 45, 5147 download the article (236 KB)
download the article Organozinc Derivatives of Deltahedral Zintl Ions: Synthesis and Characterization of closo-[E9Zn(C6H5)]3- Jose M. Goicoechea and Slavi C. Sevov, Organometallics 2006, 25, 4530 download the article (244 KB)
download the article Deltahedral Germanium Clusters: Insertion of Transition-Metal Atoms and Addition of Organometallic Fragments. Jose M. Goicoechea and Slavi C. Sevov, J. Am. Chem. Soc. 2006, 128, 4155 download the article (193 KB)

2005

download the article Synthesis of a chain of nine-atom germanium clusters accompanied with dimerization of the sequestering agent. Angel Ugrinov, Slavi C. Sevov, C. R. Chimie 2005, 8, 1878 download the article (280 KB)
download the article [(Ni-Ni-Ni)@(Ge9)2]4-: A Linear Triatomic Nickel Filament Enclosed in a Dimer of Nine-Atom Germanium Clusters. Jose M. Goicoechea and Slavi C. Sevov, Angew. Chem. Int. Ed. 2005, 127, 4026 download the article (369 KB)
download the article [(Pd-Pd)@Ge18]4-: A Palladium Dimer Inside the Largest Single-Cage Deltahedral Cluster. Jose M. Goicoechea and Slavi C. Sevov, J. Am. Chem. Soc. 2005, 127, 7676 download the article (129 KB)
Highlighted in: Science 2005, 305, 1088 (Editor's Choice section, May 20).
download the article Ligand-Free Deltahedral Clusters of Silicon in Solution: Synthesis, Structure, and Electrochemistry os Si92-. Jose M. Goicoechea and Slavi C. Sevov, Inorg. Chem. 2005, 44, 2654 download the article (108 KB)
download the article Analysis of the Effect of Spin-Orbit Coupling on the Electronic Structure and Excitation Spectrum of the Bi22- anion in (K-crypt)2Bi2 on the Basis of Relativistic Electronic Structure Calculations. D. Dai, M.-H. Whangbo, A. Ugrinov, S. C. Sevov, F. Wang, L. Li, A. Villesuzanne, A. B. Alekseyev, H.-P. Liebermann, R. J. Buenker, J. Phys. Chem. A 2005, 109, 1675 download the article (231 KB)

2004

download the article Naked Deltahedral Silicon Clusters in Solution: Synthesis and Characterization of Si93- and Si52-. Goicoechea, J. M.; Sevov, S.C. J. Am. Chem. Soc. 2004, 126(22), 6860-6861 download the article (38.8 KB)
Highlighted in: Chemistry & Industry 2004, June 21, p. 30
download the article Rationally Functionalized Deltahedral Zintl Ions: Synthesis and Characterization of [Ge9-ER3]3-, [R3E-Ge9-ER3]2-, and [R3E-Ge9-Ge9-ER3]4- (E = Ge, Sn; R = Me, Ph). Angel Ugrinov and Slavi C. Sevov Chem. Eur. J. 2004, 10, 3727-3733 download the article (213 KB)

2003

download the article Snthesis and Structure of [K-(12-crown-4)2]2[K-(12-crown-4)]2[Sn9]?en. Angel Ugrinov and Slavi C. Sevov Appl. Organomet. Chem. 2003, 17, 373-376 download the article (131 KB)
download the article [Ge9=Ge9=Ge9=Ge9]8-: A Linear Tetramer of Nine-Atom Germanium Clusters, a Nanorod. Angel Ugrinov and Slavi C. Sevov Inorg. Chem 2003, 42, 5789-5791 download the article (98.3 KB)
Highlighted in: Chemical & Engineering News 2003, Sept. 15
Highlighted in: Chemistry & Industry 2003, Oct. 20, p. 28
download the article Derivatization of Deltahedral Zintl Ions by Nucleophilic Addition: [Ph-Ge9-SbPh2]2- and [Ph2Sb-Ge9-Ge9-SbPh2]4-. Angel Ugrinov and Slavi C. Sevov J. Am. Chem. Soc. 2003, 125, 14509-14064 download the article (315 KB)

2002

download the article [Ge9=Ge9=Ge9]6-: A Linear Trimer of 27 Germanium Atoms. Angel Ugrinov and Slavi C. Sevov J. Am. Chem. Soc. 2002, 124, 10990 download the article (55.1 KB)
Highlighted in: Nachrichtenaus der Chemie 2002, p. 1332
download the article [Ph2Bi-(Ge9)-BiPh2]2-: A Deltahedral Zintl Ion Functionalized by Exo-Bonded Ligands. Angel Ugrinov and Slavi C. Sevov J. Am. Chem. Soc. 2002, 124, 2442 download the article (36.7 KB)
Highlighted in: Chemistry & Industry 2003, Aug. 4, p. 29

2001

download the article Stabilization of Ozone-like [Bi3]3- in the Heteroatomic closo-Clusters [Bi3Cr2(CO)6]3- and [Bi3Mo2(CO)6]3-. Xu, L.; Sevov, S.C. J. Am. Chem. Soc. 2001, 123, 4091 download the article (38.4 KB)

2000

download the article Heteroatomic Deltahedral Clusters of Main-Group Elements: Synthesis and Structure of the Zintl Ions [In4Bi5]3-, [InBi3]3-, and [GaBi3]3-. Xu, L.; Sevov, S.C. Inorg. Chem. 2000, 39, 5383 download the article (88.9 KB)
download the article A Naked Diatomic Molecule of Bismuth, [Bi2]2-, with a short Bi-Bi Bond: Synthesis and Structure. Xu, L.; Sevov, S.C. J. Am. Chem. Soc. 2000, 122, 1838 download the article (39.1 KB)
Highlighted in: Nachrichtenaus der Chemie 2000, p. 589

1999

download the article Oxidative Coupling of Deltahedral [Ge9]4- Zintl Ions. Xu, L; Sevov, S.C. J. Am. Chem. Soc. 1999, 121, 9245 download the article (32 KB)
Highlighted in: Chemistry & Industry 1999, Oct. 8, p. 810

publications for other projects:
Intermetallic Compounds | Hybrid Organic-Inorganic Materials

last revised: Aug 18th, 2015
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