"Welcome to The Prashant Kamat lab at the University of Notre Dame! With the help of internal and external collaborations we have established a successful multidisciplinary research program in nanostructure architectures and energy conversion processes." - Prashant Kamat

Kamat Lab News

Friday, August 30, 2019Posted by Jeff DuBose

Undergraduate Researcher Jake Drysdale Gives Poster Presentation about his project: "Halide Composition and Temperature Dependent Properties of Perovskite Solar Cells"

Click here to see the video!

Undergraduate researcher James Drysdale gives a video presentation for his poster entitled "Halide Composition and Temperature Dependent Properties of Perovskite Solar Cells" for the Notre Dame Summer Undergraduate Research Symposium.


Thursday, July 18, 2019Posted by Jeff DuBose

Come see what ND Energy has to say about associated researcher and Kamat Lab member Rebecca Scheidt

Rebecca Scheidt is entering her fourth year as a graduate student advised by Prof. Prashant Kamat in the Department of Chemistry and Biochemistry. She presented "Interfacial Charge Transfer between Excited CsPbBr3 Nanocrystals and TiO2: Charge Injection versus Photodegradation,” at the ND Energy PD&GS Luncheon in May. In 2018, Scheidt received the Patrick and Jana Eilers Graduate Student Fellowship for Energy Related Research for her project looking at cesium lead bromide perovskite nanocrystals and how they operate in a photovoltaic device stack. Because these next-generation materials absorb light so well, these nanocrystal solar cells can be placed into thin film and flexible technologies. “What I specifically look at is how they interacted with different charge transfer materials in the solar cell and whether that caused degradation under certain conditions,” Scheidt said. “In terms of making them more stable long-term, and looking at how they break down or degrade, we aim to make them more efficient overall.”

Click here to read the rest of the blurb from ND Energy

Monday, May 6, 2019Posted by Jeff DuBose

Dr. Kamat is recognized as one of the Clarivate Analytics' 2018 Highly Cited Researchers list! Congratulations, Dr. Kamat!

This list recognizes world-class researchers selected for their exceptional research performance, demonstrated by production of multiple highly cited papers that rank in the top 1% by citations for field and year in Web of Science. Click here for ND Energy's post about the Notre Dame Faculty who were awarded this prestigious honor.

Tuesday, July 5, 2016Posted by Christian Talavera

Transformation of Sintered CsPbBr3 Nanocrystals to Cubic CsPbI3 and Gradient CsPbBrxI3-x through Halide Exchange

Read the latest paper from the Kamat Lab!

Transformation of Sintered CsPbI3 Nanocrystals to Cubic CsPbI3 and Gradient CsPbBrxI3-x through Halide Exchange

Transformation of Sintered CsPbBr<sub>3</sub> Nanocrystals to Cubic CsPbI<sub>3</sub> and Gradient CsPbBr<sub>x</sub>I<sub>3-x</sub> through Halide Exchange

Abstract: All-inorganic cesium lead halide (CsPbX3, X = Br-, I-) perovskites could potentially provide comparable photovoltaic performance with enhanced stability compared to organic-inorganic lead halide species. However, small-bandgap cubic CsPbI3 has been difficult to study due to challenges forming CsPbI3 in the cubic phase. Here, a low-temperature procedure to form cubic CsPbI3 has been developed through a halide exchange reaction using films of sintered CsPbBr3 nanocrystals. The reaction was found to be strongly dependent upon temperature, featuring an Arrhenius relationship. Additionally, film thickness played a significant role in determining internal film structure at intermediate reaction times. Thin films (50 nm) showed only a small distribution of CsPbBrxI3-x species, while thicker films (350 nm) exhibited much broader distributions. Furthermore, internal film structure was ordered, featuring a compositional gradient within film. Transient absorption spectroscopy showed the influence of halide exchange on the excited state of the material. In thicker films, charge carriers were rapidly transferred to iodide-rich regions near the film surface within the first several picoseconds after excitation. This ultrafast vectorial charge-transfer process illustrates the potential of utilizing compositional gradients to direct charge flow in perovskite-based photovoltaics.

Thursday, June 23, 2016Posted by Christian Talavera

Tracking Iodide and Bromide Ion Segregation in Mixed Halide Lead Perovskites during Photoirradiation

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Tracking Iodide and Bromide Ion Segregation in Mixed Halide Lead Perovskites during Photoirradiation

 Tracking Iodide and Bromide Ion Segregation in Mixed Halide Lead Perovskites during Photoirradiation

Abstract: Mixed halide lead perovskites (e.g., CH3NH3PbBrxI3-x) undergo phase segregation creating iodide-rich and bromide-rich domains when subjected to visible irradiation. This intriguing aspect of halide ion movement in mixed halide films is now being tracked through excited-state behavior using emission and transient absorption spectroscopy tools. These transient experiments have allowed us to establish the time scale with which such separation occurs under laser irradiation (405 nm, 25 mW/cm2 to 1.7 W/cm2) as well as dark recovery. While the phase separation occurs with a rate constant of 0.1-0.3 s-1, the recovery occurs over a time period of several minutes to an hour. The relative photoluminescence quantum yield observed for Br-rich regions (em. max 530 nm) is nearly 2 orders of magnitude lower than that of I-rich regions (em. max 760 nm) and arises from the fact that I-rich regions serve as sinks for photogenerated charge carriers. Understanding such cascading charge transfer to localized sites could further enable the design of gradient halide structures in mixed halide systems.

Wednesday, June 22, 2016Posted by Christian Talavera

Intriguing Optoelectronic Properties of Metal Halide Perovskites

Read the latest paper from the Kamat Lab!

Intriguing Optoelectronic Properties of Metal Halide Perovskites

Intriguing Optoelectronic Properties of Metal Halide Perovskites

Abstract: A new chapter in the long and distinguished history of perovskites is being written with the breakthrough success of metal halide perovskites (MHPs) as solution-processed photovoltaic (PV) absorbers. The current surge in MHP research has largely arisen out of their rapid progress in PV devices; however, these materials are potentially suitable for a diverse array of optoelectronic applications. Like oxide perovskites, MHPs have ABX3 stoichiometry, where A and B are cations and X is a halide anion. Here, the underlying physical and photophysical properties of inorganic (A = inorganic) and hybrid organic-inorganic (A = organic) MHPs are reviewed with an eye toward their potential application in emerging optoelectronic technologies. Significant attention is given to the prototypical compound methylammonium lead iodide (CH3NH3PbI3) due to the preponderance of experimental and theoretical studies surrounding this material. We also discuss other salient MHP systems, including 2-dimensional compounds, where relevant. More specifically, this review is a critical account of the interrelation between MHP electronic structure, absorption, emission, carrier dynamics and transport, and other relevant photophysical processes that have propelled these materials to the forefront of modern optoelectronics research.