"Welcome to The Prashant Kamat lab at the University of Notre Dame! With the help of internal and external collaborations we have established a successful multidisciplinary research program in nanostructure architectures and energy conversion processes." - Prashant Kamat


Kamat Lab News


Thursday, June 23, 2016Posted by Christian Talavera

Tracking Iodide and Bromide Ion Segregation in Mixed Halide Lead Perovskites during Photoirradiation

Read the latest paper from the Kamat Lab!

Tracking Iodide and Bromide Ion Segregation in Mixed Halide Lead Perovskites during Photoirradiation

 Tracking Iodide and Bromide Ion Segregation in Mixed Halide Lead Perovskites during Photoirradiation

Abstract: Mixed halide lead perovskites (e.g., CH3NH3PbBrxI3-x) undergo phase segregation creating iodide-rich and bromide-rich domains when subjected to visible irradiation. This intriguing aspect of halide ion movement in mixed halide films is now being tracked through excited-state behavior using emission and transient absorption spectroscopy tools. These transient experiments have allowed us to establish the time scale with which such separation occurs under laser irradiation (405 nm, 25 mW/cm2 to 1.7 W/cm2) as well as dark recovery. While the phase separation occurs with a rate constant of 0.1-0.3 s-1, the recovery occurs over a time period of several minutes to an hour. The relative photoluminescence quantum yield observed for Br-rich regions (em. max 530 nm) is nearly 2 orders of magnitude lower than that of I-rich regions (em. max 760 nm) and arises from the fact that I-rich regions serve as sinks for photogenerated charge carriers. Understanding such cascading charge transfer to localized sites could further enable the design of gradient halide structures in mixed halide systems.


Wednesday, June 22, 2016Posted by Christian Talavera

Intriguing Optoelectronic Properties of Metal Halide Perovskites

Read the latest paper from the Kamat Lab!

Intriguing Optoelectronic Properties of Metal Halide Perovskites

Intriguing Optoelectronic Properties of Metal Halide Perovskites

Abstract: A new chapter in the long and distinguished history of perovskites is being written with the breakthrough success of metal halide perovskites (MHPs) as solution-processed photovoltaic (PV) absorbers. The current surge in MHP research has largely arisen out of their rapid progress in PV devices; however, these materials are potentially suitable for a diverse array of optoelectronic applications. Like oxide perovskites, MHPs have ABX3 stoichiometry, where A and B are cations and X is a halide anion. Here, the underlying physical and photophysical properties of inorganic (A = inorganic) and hybrid organic-inorganic (A = organic) MHPs are reviewed with an eye toward their potential application in emerging optoelectronic technologies. Significant attention is given to the prototypical compound methylammonium lead iodide (CH3NH3PbI3) due to the preponderance of experimental and theoretical studies surrounding this material. We also discuss other salient MHP systems, including 2-dimensional compounds, where relevant. More specifically, this review is a critical account of the interrelation between MHP electronic structure, absorption, emission, carrier dynamics and transport, and other relevant photophysical processes that have propelled these materials to the forefront of modern optoelectronics research.


Friday, June 17, 2016Posted by Christian Talavera

Kamat Lab Ready for Summer 2016!

Kamat Lab Summer 2016.

With only 3 days until the official start of the Summer solstice, the Kamat Lab is ready for another productive season! Stay tuned for more news on the exciting research being conducted here in the Kamat Lab!









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