Publications

H-Index of 105 (h index is the number of papers with same or greater citations)
H-Index of Living Chemists - Royal Society of Chemistry, December 2011
>38000 total citations (Impact Factor: >92 citations per paper)


Citation Report for Prashant V. Kamat * Source: ISI Web of Science - 8/13/2013

Hot off the Press

Our most recent papers...

470. Size-Dependent Photovoltaic Performance of CuInS2 Quantum Dots Sensitized Solar Cells
Jara, D. H.;Yoon, S.; Stamplecoskie, K. G.; Kamat, P. V. Chem. Mater. 2014, ASAP.

The optical and electronic properties of quantum dots (QDs) which are drastically affected by their size have major impact on their performance in devices like solar cells. We now report the size dependent solar cell performance for CuInS2 QDs capped with 1-dodecanethiol. Pyramidal shaped CuInS2 QDs with diameter between 2.9 nm and 5.3 nm have been synthesized and assembled on mesoscopic TiO2 films by electrophoretic deposition. Time resolved emission and transient absorption spectroscopy measurements have ascertained the role of internal and surface defects in determining the solar cell performance. An increase in power conversion efficiency (PCE) was observed with increasing size of QDs, with maximum values of 2.14 and 2.51% for 3.9 and 4.3 nm size particles, respectively. The drop in PCE observed for larger QDs (5.3 nm) is attributed to decreased charge separation following bandgap excitation. Since the origin of photocurrent generation in CuInS2 QDSC arises from the defect dominated charge carriers it offers the opportunity to further improve the efficiency by controlling these defect concentrations.



469. Dual Nature of the Excited State in Organic-Inorganic Lead Halide Perovskites
Stamplecoskie, K. G.; Manser, J. S.; Kamat, P. V. Energy Environ. Sci. 2014, ASAP.

The rapid increase in efficiency of methylammonium lead halide perovskite solar cells necessitates further investigation into the nature of perovskite absorption features and optical properties. Films obtained from the deposition of solutions containing lead halides and the CH3NH3+ organic cation is known to yield the CH3NH3PbI3 perovskite structure upon annealing. In examining the precursor solution used in the processing of CH3NH3PbI3 solar cells, we find that Pb2+ readily forms plumbate complexes in the presence of excess iodide ions and exhibits characteristic absorption bands at 370 (PbI3-) and 425 nm (PbI42-). Through comparative spectral analysis of the absorption features of charge transfer complexes in the solution phase and the final solid-state perovskite films, we are able to fully classify the absorption features in the excited state of CH3NH3PbI3 across the transient absorption spectrum recorded following laser pulse excitation. In particular, we attribute the broad photoinduced absorption to a charge-transfer excited state, and show correlation between the photoinduced absorption and 480 nm bleach signals. These observations lead us to propose a band structure composed of two distinct transitions that is consistent with the various spectral features and kinetic behavior of the CH3NH3PbI3 excited state. Characterization of this unique dual excited state nature provides further insight into the optoelectronic behavior of hybrid lead halide perovskite films and thus aids in elucidating their exceptional photovoltaic properties.



468. The Origin of Catalytic Effect in the Reduction of CO2 at Nanostructured TiO2 Films
Ramesha, G. K.; Brennecke, J. F.; Kamat, P. V. ACS Catal. 2014, 4 (9), 3249–3254.

Electrocatalytic activity of mesoscopic TiO2 films towards the reduction of CO2 is probed by depositing a nanostructured film on a glassy carbon electrode. The one-electron reduction of CO2 in acetonitrile seen at an onset potential of -1.1 V (vs. NHE) is ~0.5 V lower than the one observed with a glassy carbon electrode. The electrocatalytic role of TiO2 is elucidated through spectroelectrochemistry and product analysis. Ti3+ species formed when TiO2 film is subjected to negative potentials have been identified as active reduction sites. Binding of CO2 to catalytically active Ti3+ followed by the electron transfer facilitates the initial one-electron reduction process. Methanol was the primary product when the reduction was carried out in wet acetonitrile.



467. Band Filling with Free Charge Carriers in Organometal Halide Perovskites
Manser, J. S.; Kamat, P. V. Nat. Photon. 2014, 8, 737–743.

The unique and promising properties of semiconducting organometal halide perovskites have brought these materials to the forefront of solar energy research. Here, we present new insights into the excited-state properties of CH3>NH3PbI3 thin films through femtosecond transient absorption spectroscopy measurements. The photoinduced bleach recovery at 760 nm reveals that band-edge recombination follows second-order kinetics, indicating that the dominant relaxation pathway is via recombination of free electrons and holes. Additionally, charge accumulation in the perovskite films leads to an increase in the intrinsic bandgap that follows the Burstein–Moss band filling model. Both the recombination mechanism and the band-edge shift are studied as a function of the photogenerated carrier density and serve to elucidate the behaviour of charge carriers in hybrid perovskites. These results offer insights into the intrinsic photophysics of semiconducting organometal halide perovskites with direct implications for photovoltaic and optoelectronic applications.



466. Is Graphene a Stable Platform for Photocatalysis? Mineralization of Reduced Graphene Oxide with UV-Irradiated TiO2 Nanoparticles
Radich J. G.; Krenselewski, A.; Zhu, J.; Kamat, P. V. Chem. Mater. 2014, 26 (15), 4662–4668.

The recent thrust in utilizing reduced graphene oxide (RGO) as a support for nanostructured catalyst particles has led to the claims of improved efficiency in solar cells, fuel cells, and photocatalytic degradation of pollutants. Specifically, the robust TiO2 system is often coupled with RGO to improve charge separation and facilitate redox reactions. Here we probe the stability of RGO in the presence of UV-excited TiO2 in aqueous media and establish its reactivity towards OH radicals, a primary oxidant generated at the TiO2 surface. By probing changes in absorption, morphology and total organic carbon content (TOC) we conclusively demonstrate the vulnerability of RGO towards OH attack and raise the concern of its use in many applications where OH are likely to be formed. On the other hand, the OH radical-mediated mineralization could also enable new approaches in tackling environmental remediation of nanocarbons such as RGO, carbon nanotubes, and fullerenes.



All Publications

Big Impact

Our most cited papers...

1. Photochemistry on nonreactive and reactive (semiconductor) surfaces.
P.V. Kamat Chem. Rev. 1993, 93, 267-300. NDRL 3523
Cited 1262 times


2. Photophysical, photochemical and photocatalytic aspects of metal nanoparticles.
J. Phys. Chem. B 2002, 106, 7729-7744. NDRL 4374 (Feature Article)
Cited 1128 times


3. Meeting the Clean Energy Demand: Nanostructure Architectures for Solar Energy Conversion.
Kamat, P. V. J. Phys. Chem. C 2007, 111 2834-2860. (Feature Article in February 22 2007 issue) NDRL 4697
Cited 946 times


4. Quantum Dot Solar Cells. Semiconductor Nanocrystals as Light Harvestors.
Kamat, P. V. J. Phys. Chem. C 2008, 112, 18737-18753. NDRL 4770 (Centennial Feature Article)
Cited 888 times


5. Quantum Dot Solar Cells. Harvesting Light Energy with CdSe Nanocrystals Molecularly Linked to Mesoscopic TiO2 Films.
Robel, I., Subramanian, V., Kuno, M. and Kamat, P. V. J. Am. Chem. Soc. 2006, 128 (7), 2385-2393. NDRL 4627
Cited 853 times


20 Most Cited

Editorial Publications

Editorials on scientific research and publication...

33. Mastering the Art of Scientific Publication: Twenty Papers with 20/20 Vision on Publishing
Kamat, P. V.; Buriak, J. M.; Schatz, G. C.; Weiss, P. S. J. Phys. Chem. Lett. 2014, 5 (20), 3519-3521.


32. What's in a Name?
Kamat, P. V.; Schatz, G. C. J. Phys. Chem. Lett. 2014, 5 (16), 2879–2879.


31. Best practices for reporting on heterogeneous photocatalysis
Buriak, J. M.; Kamat, P. V.; Schanze, K. S. ACS Appl. Mater. Interfaces 2014, 6 (15), 11815–11816.


30. Why Did You Accept My Paper?
P.V. Kamat, O. Prezhdo, J.-E. Shea, G. Scholes, F. Zaera, T. Zwier, G. C. Schatz, J. Phys. Chem. Lett. 2014, 5 (14), 2443-2443.


29. Graphical Excellence
P.V. Kamat, G. V. Hartland, G. C. Schatz, J. Phys. Chem. Lett. 2014, 5 (12), 2118-2120.


Editorials